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4,4′-Diphenylmethane diisocyanate(CAS#101-68-8)

Ipropati yeMichiza:

Ifomula yeemolekyuli I-C15H10N2O2
IMisa yeMolar 250.25
Ukuxinana 1.19
Indawo yokunyibilika 38-44 °C
Indawo yeBoling 392 °C
Indawo yokuflasha 196 °C
Ukunyibilika kwamanzi iyabola
Ukunyibilika 2g/l (ukubola)
Uxinzelelo loMphunga 0.066 hPa (20 °C)
Imbonakalo icocekile
Ubunzima obuthile 1.180
Umbala Mhlophe ukuya Phantse mhlophe
Umda wokuvezwa I-TLV-TWA 0.051 mg / m3 (0.005 ppm) (ACGIH kunye ne-NIOSH); isilingi (umoya) 0.204mg/m3 (0.02 ppm)/10 min (NIOSH neOSHA); IDLH 102 mg/m3 (10 ppm).
I-BRN 797662
Imeko yoGcino -20°C
Uzinzo Izinzile. Ukutsha. Ayihambelani ne-oxidizing agents ezinamandla. Iphendula ngobundlobongela kunye notywala.
Inovakalelo Ukufuma okuSensitive/Lachrymatory
Umda wokuqhushumba 0.4%(V)
Refractive Index 1.5906 (uqikelelo)
IiPropati zoMzimba kunye nezeMichiza Uphawu luluthuthu olutyheli olutyhidiweyo oluqinileyo kunye nevumba elinamandla elicaphukisayo.
indawo yokubilisa 196 ℃
indawo yokukhenkceza 37 ℃
ukuxinana kwesihlobo 1.1907
Inyibilika kwi-acetone, ibenzene, i-kerosene, i-nitrobenzene.indawo yeflash: 200-218

isalathiso se-refractive: 1.5906

Sebenzisa Isetyenziswa kwiiplastiki kunye namashishini erabha kunye nokunamathelisa

Iinkcukacha zeMveliso

Iithegi zeMveliso

Iikhowudi zoMngcipheko I-R42/43 – Inokubangela uvakalelo ngokuphefumla kunye nokudibana nolusu.
R36/37/38 – Ukucaphuka kwamehlo, inkqubo yokuphefumla kunye nolusu.
I-R20 – Inobungozi ngokuphefumla
R48/20 -
R40 – Ubungqina obuncinane besiphumo somhlaza
Inkcazelo yoKhuseleko S45 - Kwimeko yengozi okanye ukuba uziva ungaphilanga, funa iingcebiso zonyango ngokukhawuleza (bonisa ileyibhile nanini na kunokwenzeka.)
S36/37 – Nxiba iimpahla ezifanelekileyo zokukhusela kunye neeglavu.
S23 – Musa ukuphefumla umphunga.
Izazisi ze-UN 2206
WGK eJamani 1
RTECS NQ9350000
I-TSCA Ewe
Ikhowudi ye-HS 29291090
Inqaku Lengozi Inetyhefu/I-Corrosive/Lachrymatory/Inobuzaza bokufuma
IKlasi yeeNgozi 6.1
Iqela lokuPakisha II
Ubutyhefu I-LD50 ngomlomo kuMvundla: > 5000 mg/kg LD50 dermal Rabbit > 9000 mg/kg

 

Intshayelelo

I-Diphenylmethane-4,4'-disocyanate, eyaziwa ngokuba yi-MDI. I-organic compound kwaye luhlobo lwe-benzodisocyanate compounds.

 

Umgangatho:

1. Inkangeleko: I-MDI ayinambala okanye ukukhanya okuqinileyo okutyheli.

2. Ukunyibilika: I-MDI iyanyibilika kwizinyibilikisi zendalo ezifana neekhilobhoni eziklorini kunye neehydrocarbon ezinuka kamnandi.

 

Sebenzisa:

Isetyenziswa njengento ekrwada kwiikhompawundi polyurethane. Inokusabela nge-polyether okanye i-polyurethane polyols ukwenza i-polyurethane elastomers okanye iipolymers. Esi sixhobo sinoluhlu olubanzi lwezicelo kulwakhiwo, iimoto, ifenitshala, kunye nezihlangu, phakathi kwabanye.

 

Indlela:

Indlela ye-diphenylmethane-4,4'-diisocyanate ikakhulu ukusabela i-aniline kunye ne-isocyanate ukufumana i-aniline-based isocyanate, kwaye emva koko idlule kwi-diazotization reaction kunye ne-denitrification ukufumana imveliso ekujoliswe kuyo.

 

Ulwazi ngoKhuseleko:

1. Kulumkele ukudibana ngqo nolusu kwaye uxhotyiswe ngezixhobo ezifanelekileyo zokuzikhusela ezinjengeeglavu, iiglasi kunye nempahla yokuzikhusela.

2. Ukungenisa umoya: Gcina iimeko ezifanelekileyo zokungenisa umoya ngexesha lokusebenza.

3. Ugcino: Xa ugcina, kufuneka lutywinwe kwaye lugcinwe kude nemithombo yomlilo, imithombo yobushushu kunye neendawo apho imithombo yokutshisa iyenzeka khona.

4. Ukulahlwa kwenkunkuma: Inkunkuma kufuneka iphathwe kakuhle kwaye ilahlwe, kwaye akufanele ilahlwe ngokuthanda kwayo.

Xa uphatha izinto zeekhemikhali, kufuneka ziphathwe ngokungqongqo ngokuhambelana neenkqubo zebhubhoratri kunye nezikhokelo zokhuseleko, kwaye ngokuhambelana nemithetho kunye nemimiselo efanelekileyo.


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