iphepha_ibhena

imveliso

I-Benzidine(CAS#92-87-5)

Ipropati yeMichiza:

Ifomula yeemolekyuli C12H12N2
IMisa yeMolar 184.24
Ukuxinana 1.25
Indawo yokunyibilika 127-128°C
Indawo yeBoling 402°C
Indawo yokuflasha 11°C
Ukunyibilika kwamanzi Inyibilika kancinci. <0.1 g/100 mL ku-22 ºC
Ukunyibilika Inyibilika kwi-ethanol (US EPA, 1985) kunye ne-ether (1 g/50 mL) (Windholz et al., 1983)
Uxinzelelo loMphunga Ngokusekelwe kwixabiso elithile lokuxinana komphunga we-6.36 (Sims et al., 1988), uxinzelelo lomphunga lubalwe ukuba lube ngu-0.83 kwi-20 °C.
Imbonakalo icocekile
Umbala Umgubo ongwevu-tyheli, umgubo wekristale; iikristale ezimhlophe okanye sltlyreddish, umgubo
Umda wokuvezwa Ngenxa yokuba iyi-carcinogen kwaye ifunxeka ngokulula eluswini, akukho TLV eyabelweyo. Ukuvezwa kufuneka kube bubuncinci obucacileyo.I-Recognized Human Carcinogen (ACGIH);I-Carcinogen yomntu (MSHA); Umhlaza (O
Merck 13,1077
I-BRN 742770
pKa 4.66(nge-30℃)
Imeko yoGcino 2-8°C
Uzinzo Izinzile. Ukutsha. Ayihambelani ne-oxidizing agents ezinamandla.
Refractive Index 1.6266 (uqikelelo)
IiPropati zoMzimba kunye nezeMichiza I-crystalline powder emhlophe okanye ebomvu. Indawo yokunyibilika 125 ℃, indawo yokubila 400 ℃,(98.7kPa), ingxinano 1.250(20/4 ℃), inyibilika kwi-ethanol ebilayo, i-acetic acid kunye ne-dilute hydrochloric acid, inyibilika kancinane kwi-ether, inyibilika kancinane emanzini abilayo, inyibilika emanzini abandayo. Umbala uba mnyama emoyeni nasekukhanyeni. Ii-reagents zokuhlalutya zihlala ziyi-benzidine hydrochloride okanye i-acetate ene-solubility ephezulu, kwaye i-sulfate idla ngokusetyenziswa kwishishini. I-Benzidine acetate imhlophe okanye iphantse i-crystals emhlophe, i-soluble emanzini, i-acetic acid kunye ne-hydrochloric acid, kwaye isetyenziswe njengesalathisi [36341-27-2]. ibenzidine hydrochloride [531-85-1]. I-Benzidine sulfate yi-crystalline powder emhlophe okanye i-crystal encinci efana ne-crystal, i-soluble kwi-ether, i-soluble kancinane kakhulu emanzini, i-asidi edibeneyo kunye notywala [21136-70-9].

Iinkcukacha zeMveliso

Iithegi zeMveliso

Iikhowudi zoMngcipheko I-R45 – Isenokubangela umhlaza
I-R22 – Iyingozi xa iginyiwe
R50/53 – Ityhefu kakhulu kwizinto eziphila emanzini, inokubangela iziphumo ezibi zexesha elide kwindawo ehlala emanzini.
R52/53 – Iyingozi kwizinto eziphila emanzini, inokubangela iziphumo ezibi zexesha elide kwindawo ehlala emanzini.
R39/23/24/25 -
I-R23/24/25 – Ityhefu ngokuphefumla, xa udibana nesikhumba naxa uginyiwe.
I-R11 – Iyatsha kakhulu
R36/37/38 – Ukucaphuka kwamehlo, inkqubo yokuphefumla kunye nolusu.
I-R20/21/22 – Iyingozi ngokuphefumla, xa udibana nolusu naxa uginyiwe.
R51/53 – Ityhefu kwizinto eziphila emanzini, inokubangela iziphumo ezibi zexesha elide kwindawo ehlala emanzini.
R67 – Umphunga unokubangela ukozela kunye nesiyezi
Inkcazelo yoKhuseleko S53 – Kuphephe ukuba sesichengeni – fumana imiyalelo eyodwa phambi kokusetyenziswa.
S45 - Kwimeko yengozi okanye ukuba uziva ungaphilanga, funa iingcebiso zonyango ngokukhawuleza (bonisa ileyibhile nanini na kunokwenzeka.)
S60 – Esi sixhobo kunye nesingxobo saso kufuneka silahlwe njengenkunkuma eyingozi.
S61 –Kuphephe ukukhutshelwa kokusingqongileyo. Jonga kwimiyalelo ekhethekileyo / kumaphepha edatha yokhuseleko.
S36/37 – Nxiba iimpahla ezifanelekileyo zokukhusela kunye neeglavu.
S16 – Gcina kude kwimithombo yomlilo.
S7 – Gcina isikhongozeli sivalwe ngokuqinileyo.
S36 – Nxiba iimpahla ezifanelekileyo ezikhuselayo.
S26 – Xa udibana namehlo, hlambulula ngokukhawuleza ngamanzi amaninzi kwaye ufune iingcebiso zonyango.
Izazisi ze-UN UN 1885 6.1/PG 2
WGK eJamani 3
RTECS DC9625000
FLUKA BRAND F IIKHOWUDI 8
Ikhowudi ye-HS 29215900
IKlasi yeeNgozi 6.1(a)
Iqela lokuPakisha II
Ubutyhefu I-Acute oral LD50 yeegundane 214 mg / kg, iigundane 309 mg / kg (icatshulwa, RTECS, 1985).

 

Intshayelelo

I-Benzidine (eyaziwa ngokuba yi-diphenylamine) yi-organic compound. Oku kulandelayo sintshayelelo kubume bayo, ukusetyenziswa, iindlela zokwenza kunye nolwazi lokhuseleko:

 

Umgangatho:

- Imbonakalo: I-Benzidine yikristale emhlophe ukuya kokukhanya etyheli.

-Ukunyibilika: akunyibiliki emanzini, kunyibilika kwizinyibilikisi zendalo ezifana neealkoholi, ii-ethers, njl.

- Uphawu: I-electrophile eneempawu ze-electrophilic substitution reaction.

 

Sebenzisa:

- I-Benzidine isetyenziswa ngokubanzi kwintsimi ye-organic synthesis. Ingasetyenziswa njengento eluhlaza kunye ne-synthetic intermediate kwiikhemikhali ezinje ngedayi, ii-pigments, iiplastiki, njl.

 

Indlela:

- I-Benzidine ilungiselelwe ngokwesiko ngokunciphisa i-dinitrobiphenyl, ukupheliswa kwemisebe ye-haloaniline, njl.

- Iindlela zokulungiselela zale mihla zibandakanya ukuhlanganiswa kwe-organic yee-amines ezinuka kamnandi, njengokusabela kwe-substrate diphenyl ether kunye ne-amino alkanes.

 

Ulwazi ngoKhuseleko:

- I-Benzidine inetyhefu kwaye inokubangela ukucaphuka kunye nomonakalo kumzimba womntu.

- Xa uphethe i-benzidine, kufuneka kuthathelwe ingqalelo ukuphepha ukudibanisa kwesikhumba kunye nokuphefumla, kunye nezixhobo zokukhusela ezifana neeglavu, iiglasi zokukhusela, kunye neemaski zokukhusela kufuneka zigqitywe xa kuyimfuneko.

- Xa i-benzidine idibana nolusu okanye amehlo, kufuneka ihlanjwe ngokukhawuleza ngamanzi amaninzi.

-Xa ugcina kwaye usebenzisa i-benzidine, lumkela ukuthintela ukudibana nezinto eziphilayo kunye nee-oxidants ukuthintela umlilo okanye ugqabhuko-dubulo.

 


  • Ngaphambili:
  • Okulandelayo:

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