iphepha_ibhena

imveliso

I-Chloroacetyl chloride(CAS#79-04-9)

Ipropati yeMichiza:

Ifomula yeemolekyuli C2H2Cl2O
IMisa yeMolar 112.94
Ukuxinana 1.419g/mLat 20°C
Indawo yokunyibilika −22°C(lit.)
Indawo yeBoling 105-106°C(lit.)
Indawo yokuflasha >100°C
Ukunyibilika kwamanzi iyasabela
Ukunyibilika Idibene ne-ethyl ether, i-acetone, ibenzene kunye ne-carbon tetrachloride.
Uxinzelelo loMphunga 60 mm Hg ( 41.5 °C)
Ukuxinana komphunga 3.9 (vs umoya)
Imbonakalo Ulwelo
Umbala Icacile engenambala ukuya kumthubi kancinane
Umda wokuvezwa ACGIH: TWA 0.05 ppm; STEL 0.15 ppm (Skin)NIOSH: IDLH 1.3 ppm; TWA 0.05 ppm(0.2 mg/m3)
Merck 14,2067
I-BRN 605439
Imeko yoGcino Gcina eRT.
Uzinzo Izinzile. Ukungahambelani neziseko ezinamandla, ii-alcohols, ii-oxidizing agents ezinamandla. Isenokusabela ngobundlobongela ekuvenweni kwamanzi okanye ukufuma.
Inovakalelo Ukungenwa kukufuma
Refractive Index n20/D 1.453(lit.)
IiPropati zoMzimba kunye nezeMichiza Iimpawu zolwelo olungenambala okanye olutyheli, kukho ukucaphuka okunamandla.
Indawo yokunyibilika
indawo yokubilisa 107 ℃
indawo yokukhenkceza -22.5 ℃
ukuxinana kobudlelwane 1.4202
refractive index 1.4530
Ukunyibilika: ukunyibilika kwibenzene, carbon tetrachloride, ether kunye nechloroform.
Sebenzisa Isetyenziswa kwezamayeza, isibulali zinambuzane, isenokusetyenziswa njengesinyibilikisi, isikhenkcezisi, isincedisi sedayi kunye nezongezo zeoyile zokuthambisa.

Iinkcukacha zeMveliso

Iithegi zeMveliso

Iikhowudi zoMngcipheko I-R14 – Iphendula ngobundlobongela emanzini
I-R23/24/25 – Ityhefu ngokuphefumla, xa udibana nesikhumba naxa uginyiwe.
I-R35 – Ibangela ukutsha okumandundu
R48/23 -
R50 – Inetyhefu kakhulu kwizinto eziphila emanzini
I-R29 – Ukudibana namanzi kukhulula igesi eyityhefu
Inkcazelo yoKhuseleko S9 – Gcina isikhongozeli kwindawo engenamoya.
S26 – Xa udibana namehlo, hlambulula ngokukhawuleza ngamanzi amaninzi kwaye ufune iingcebiso zonyango.
S36/37/39 – Nxiba iimpahla ezikhuselayo ezifanelekileyo, iiglavu kunye nokhuseleko lwamehlo/ubuso.
S45 - Kwimeko yengozi okanye ukuba uziva ungaphilanga, funa iingcebiso zonyango ngokukhawuleza (bonisa ileyibhile nanini na kunokwenzeka.)
S61 –Kuphephe ukukhutshelwa kokusingqongileyo. Jonga kwimiyalelo ekhethekileyo / kumaphepha edatha yokhuseleko.
S7/8 -
Izazisi ze-UN UN 1752 6.1/PG 1
WGK eJamani 3
RTECS AO6475000
I-TSCA Ewe
Ikhowudi ye-HS 29159000
IKlasi yeeNgozi 6.1
Iqela lokuPakisha I

 

Intshayelelo

I-Monochloroacetyl chloride (eyaziwa nangokuthi i-chloroyl chloride, i-acetyl chloride) yi-organic compound. Iimpawu zayo zezi zilandelayo:

 

1. Imbonakalo: ulwelo olungenambala okanye olutyheli;

2. Ivumba: ivumba elikhethekileyo elibukhali;

3. Ubuninzi: 1.40 g / mL;

 

I-Monochloroacetyl chloride iqhele ukusetyenziswa kwi-organic synthesis kwaye inokusetyenziswa kulandelayo:

 

1. Njenge-acylation reagent: ingasetyenziselwa i-esterification reaction, ephendula i-asidi kunye notywala ukwenza i-ester;

2. Njenge-acetylation reagent: ingathatha indawo ye-athomu ye-hydrogen esebenzayo kunye neqela le-acetyl, njengokuqaliswa kwamaqela asebenzayo e-acetyl kwi-aromatics compounds;

3. Njenge-reagent ye-chlorine: inokwazisa ii-athomu zeklorini egameni le-ion chloride;

4. Isetyenziselwa ukulungisa ezinye izinto eziphilayo, ezifana ne-ketones, aldehydes, acids, njl.

 

I-Monochloroacetyl chloride idla ngokulungiswa ngezi ndlela zilandelayo:

 

1. Ilungiswa ngokusabela kwe-acetyl chloride kunye ne-trichloride, kwaye iimveliso zokusabela ziyi-monochloroacetyl chloride kunye ne-trichloroacetic acid:

C2H4O + Cl2O3 → CCl3COCl + ClOCOOH;

2. Ukusabela ngokuthe ngqo kwe-acetic acid ngeklorini ukuvelisa i-monochloroacetyl chloride:

C2H4O + Cl2 → CCl3COCl + HCl.

 

Xa usebenzisa i-monochloroacetyl chloride, le ngcaciso yokhuseleko ilandelayo kufuneka iqatshelwe:

 

1. Inevumba elibi kunye ne-steam, kwaye kufuneka iqhutywe kwindawo engenamoya;

2. Nangona ingenakutsha, iya kusabela ngobundlobongela xa idibana nomthombo wokutshisa, ukuvelisa iigesi ezinetyhefu, kwaye kufuneka igcinwe kude namadangatye avulekileyo;

3. Xa usebenzisa kunye nokugcina, kuyimfuneko ukuphepha ukudibanisa nee-oxidants ezinamandla, i-alkalis, i-iron powder kunye nezinye izinto zokuthintela ukuphendula okuyingozi;

4. Iyacaphukisa ulusu, amehlo kunye nenkqubo yokuphefumula, kwaye kufuneka iqhutywe ngeeglavu, izibuko kunye neemaski zokukhusela;

5. Kwimeko yokuphefumla ngengozi okanye ukudibana, hlamba indawo echaphazelekayo ngokukhawuleza kwaye ufune uncedo lwezonyango ukuba kukho naziphi na iimpawu.


  • Ngaphambili:
  • Okulandelayo:

  • Bhala umyalezo wakho apha kwaye uwuthumele kuthi